NMR Spectroscopy in Inorganic Chemistry

Author: Jonathan A. Iggo

Publisher: Oxford University Press, USA

ISBN: 9780198558903

Category: Science

Page: 87

View: 2098

Nuclear Magnetic Resonance (NMR) spectroscopy is the most important characterization technique in synthetic chemistry today. By giving a simple overview of the relevant theory, in non-mathematical terms, and avoiding the 'pattern recognition' approach frequently adopted, this book demystifies NMR. It contains examples from many different areas of Inorganic Chemistry which are closely related to the theory described.

Applications of Nuclear Magnetic Resonance Spectroscopy in Organic Chemistry

Author: L. M. Jackman,S. Sternhell

Publisher: Elsevier

ISBN: 1483280942

Category: Science

Page: 474

View: 456

Application of Nuclear Magnetic Resonance Spectroscopy in Organic Chemistry, Second Edition covers the theoretical background necessary for the intelligent application of NMR spectroscopy to common problems encountered in organic chemistry. This book is composed of five parts, and begins with introduction to the theory and practice of nuclear magnetic resonance. The succeeding chapter deals with the theory of chemical effects in NMR spectroscopy. These topics are followed by a discussion on the application of chemical shift to organic compound analysis and the principles of the spin-spin coupling .The final chapter considers the applications of time- dependent phenomena in NMR spectroscopy. This book will prove useful to analytical chemists and researchers in the allied fields.

NMR and Chemistry

An introduction to modern NMR spectroscopy, Fourth Edition

Author: J.W. Akitt,B. E. Mann

Publisher: CRC Press

ISBN: 1351991124

Category: Science

Page: 400

View: 730

Keeping mathematics to a minimum, this book introduces nuclear properties, nuclear screening, chemical shift, spin-spin coupling, and relaxation. It is one of the few books that provides the student with the physical background to NMR spectroscopy from the point of view of the whole of the periodic table rather than concentrating on the narrow applications of 1H and 13C NMR spectroscopy. Aids to structure determination, such as decoupling, the nuclear Overhauser effect, INEPT, DEPT, and special editing, and two dimensional NMR spectroscopy are discussed in detail with examples, including the complete assignment of the 1H and 13C NMR spectra of D-amygdain. The authors examine the requirements of a modern spectrometer and the effects of pulses and discuss the effects of dynamic processes as a function of temperature or pressure on NMR spectra. The book concludes with chapters on some of the applications of NMR spectroscopy to medical and non-medical imaging techniques and solid state chemistry of both I = F1/2 and I > F1/2 nuclei. Examples and problems, mainly from the recent inorganic/organometallic chemistry literature support the text throughout. Brief answers to all the problems are provided in the text with full answers at the end of the book.

Shriver and Atkins' Inorganic Chemistry

Author: Peter Atkins

Publisher: Oxford University Press, USA

ISBN: 0199236178

Category: Science

Page: 824

View: 3975

Inorganic Chemistry fifth edition represents an integral part of a student's chemistry education. Basic chemical principles are set out clearly in 'Foundations' and are fully developed throughout the text, culminating in the cutting-edge research topics of the 'Frontiers', which illustrate the dynamic nature of inorganic chemistry.

Spectroscopy in Inorganic Chemistry

Author: C.N.R. Rao

Publisher: Elsevier

ISBN: 032315090X

Category: Science

Page: 424

View: 555

Spectroscopy in Inorganic Chemistry, Volume I describes the innovations in various spectroscopic methods that are particularly effective in inorganic chemistry studies. This volume contains nine chapters; each chapter discusses a specific spectroscopic method, their fundamental principles, methods, instrumentation, advantages disadvantages, and application. Chapter 1 covers some of the general principles and experiments that have been used in the recording and interpretation of crystal spectra of molecules that contain transition-metal ions. Chapter 2 illustrates the application of spectroscopic techniques to the photochemistry of small inorganic molecules, non-transition-metal compounds, and transition-metal complexes. The remaining chapters examine several spectroscopic methods, such as matrix isolation, mass, soft X-ray, and Mössbauer spectroscopies, high-resolution NMR, and nuclear quadrupole resonance, with a particular emphasis on their effective application in inorganic chemistry studies. This book will be of great benefit to inorganic chemists, spectroscopists, and inorganic chemistry teachers and students.

NMR Spectroscopy

Basic Principles, Concepts and Applications in Chemistry

Author: Harald Günther

Publisher: John Wiley & Sons

ISBN: 3527674772

Category: Science

Page: 734

View: 7149

Nuclear magnetic resonance (NMR) spectroscopy is one of the most powerful and widely used techniques in chemical research for investigating structures and dynamics of molecules. Advanced methods can even be utilized for structure determinations of biopolymers, for example proteins or nucleic acids. NMR is also used in medicine for magnetic resonance imaging (MRI). The method is based on spectral lines of different atomic nuclei that are excited when a strong magnetic field and a radiofrequency transmitter are applied. The method is very sensitive to the features of molecular structure because also the neighboring atoms influence the signals from individual nuclei and this is important for determining the 3D-structure of molecules. This new edition of the popular classic has a clear style and a highly practical, mostly non-mathematical approach. Many examples are taken from organic and organometallic chemistry, making this book an invaluable guide to undergraduate and graduate students of organic chemistry, biochemistry, spectroscopy or physical chemistry, and to researchers using this well-established and extremely important technique. Problems and solutions are included.

Solid-state NMR Spectroscopy of Inorganic Materials

Author: John J. Fitzgerald

Publisher: Amer Chemical Society

ISBN: 9780841236028

Category: Science

Page: 422

View: 5758

This book strikes a balance between state-of-the-art solid-state NMR techniques and the applications of these techniques to problems in materials science. The applications focus on modern inorganic materials such as metal oxides, catalysts, zeolites, glasses, ceramics, semiconductors, ion conductors, superconductors, and composites. The book features chapters on multiple-quantum MAS NMR, dynamic-angle spinning NMR for quadrupolar nuclides, and two-dimensional NMR methods. It includes an introductory chapter that provides an a thorough and integrated overview of the field, complete with numerous references.

Inorganic Chemistry

Author: Catherine E. Housecroft,A. G. Sharpe

Publisher: Pearson Education

ISBN: 9780130399137

Category: Science

Page: 949

View: 4544

Inorganic Chemistry "Catherine E. Housecroft and Alan G. Sharpe" This book has established itself as a leading textbook in the subject by offering a fresh and exciting approach to the teaching of modern inorganic chemistry. It gives a clear introduction to key principles with strong coverage of descriptive chemistry of the elements. Special selected topics chapters are included, covering inorganic kinetics and mechanism, catalysis, solid state chemistry and bioinorganic chemistry. A new full-colour text design and three-dimensional illustrations bring inorganic chemistry to life. Topic boxes have been used extensively throughout the book to relate the chemistry described in the text to everyday life, the chemical industry, environmental issues and legislation, and natural resources. Teaching aids throughout the text have been carefully designed to help students learn effectively. The many worked examples take students through each calculation or exercise step by step, and are followed by related self-study exercises tackling similar problems with answers to help develop their confidence. In addition, end-of-chapter problems reinforce learning and develop subject knowledge and skills. Definitions boxes and end-of-chapter checklists provide excellent revision aids, while further reading suggestions, from topical articles to recent literature papers, will encourage students to explore topics in more depth. New to this edition Many more self-study exercises have been introduced throughout the book with the aim of making stronger connections between descriptive chemistry and underlying principles. Additional 'overview problems' have been addedto the end-of-chapter problem sets. The descriptive chemistry has been updated, with many new results from the literature being included. Chapter 4 Bonding in polyatomic molecules, has been rewritten with greater emphasis on the use of group theory for the derivation of ligand group orbitals and orbital symmetry labels. There is more coverage of supercritical fluids and 'green' chemistry. The new full-colour text design enhances the presentation of the many molecular structures and 3-D images. Supporting this edition Companion website featuring multiple-choice questions and rotatable 3-D molecular structures, available at "www.rearsoned.co.uk/housecroft," For full information, including details of lecturer material, see the Contents list inside the book. ASolutions Manual, written by Catherine E. Housecroft, with detailed solutions to all end-of-chapter problems within the text is available for purchase separately ISBN 0131 39926 8. "Catherine E. Housecroft" is Professor of Chemistry at the University of Basel, Switzerland. She is the author of a number of textbooks and has extensive teaching experience in the UK, Switzerland, South Africa and the USA. "Alan G. Sharpe" is a Fellow of Jesus College, University of Cambridge, UK and has had many years of experience teaching inorganic chemistry to undergraduates

Magnetic Resonance in Colloid and Interface Science

Author: J. Fraissard,Olga Lapina

Publisher: Springer Science & Business Media

ISBN: 9401005346

Category: Science

Page: 664

View: 6555

Magnetic resonance techniques are especially interesting in the study of colloids and interfaces due to their unique ability to elucidate structure, dynamics and function at the atomic and molecular level. This book illustrates the most up to date applications of innovative NMR and EPR techniques, including magnetic resonance imaging and microscopy, to gas-solid and liquid-solid interfaces, organic and biological surfaces, microemulsions, liquid crystals, membranes, structure and dynamics of polymers and micellar systems, and diffusion in heterogeneous systems. A compendium of advanced NMR and EPR techniques and a state of the art description of the power of advanced new methodologies for the study of molecular dynamics and interfaces.

Structural Methods in Molecular Inorganic Chemistry

Author: D. W. H. Rankin,Norbert Mitzel,Carole Morrison

Publisher: John Wiley & Sons

ISBN: 1118462882

Category: Science

Page: 496

View: 4084

Determining the structure of molecules is a fundamental skillthat all chemists must learn. Structural Methods in MolecularInorganic Chemistry is designed to help readers interpretexperimental data, understand the material published in modernjournals of inorganic chemistry, and make decisions about whattechniques will be the most useful in solving particular structuralproblems. Following a general introduction to the tools and concepts instructural chemistry, the following topics are covered indetail: • computational chemistry • nuclear magnetic resonance spectroscopy • electron paramagnetic resonance spectroscopy • Mössbauer spectroscopy • rotational spectra and rotational structure • vibrational spectroscopy • electronic characterization techniques • diffraction methods • mass spectrometry The final chapter presents a series of case histories,illustrating how chemists have applied a broad range of structuraltechniques to interpret and understand chemical systems. Throughout the textbook a strong connection is made betweentheoretical topics and the real world of practicing chemists. Eachchapter concludes with problems and discussion questions, and asupporting website contains additional advanced material. Structural Methods in Molecular Inorganic Chemistry is anextensive update and sequel to the successful textbookStructural Methods in Inorganic Chemistry by Ebsworth,Rankin and Cradock. It is essential reading for all advancedstudents of chemistry, and a handy reference source for theprofessional chemist.

Advances in Inorganic Chemistry

Author: N.A

Publisher: Academic Press

ISBN: 9780080578903

Category: Science

Page: 480

View: 4325

Advances in Inorganic Chemistry presents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry ranging from bio-inorganic to solid state studies. Thisacclaimed serial features reviews written by experts in the area and is an indispensable reference to advanced researchers. Each volume of Advances in Inorganic Chemistry contains an index, and each chapter is fully referenced.

Physical Inorganic Chemistry

Principles, Methods, and Models

Author: Andreja Bakac

Publisher: John Wiley & Sons

ISBN: 9780470602515

Category: Science

Page: 528

View: 6189

Physical Inorganic Chemistry contains the fundamentals of physical inorganic chemistry, including information on reaction types, and treatments of reaction mechanisms. Additionally, the text explores complex reactions and processes in terms of energy, environment, and health. This valuable resource closely examines mechanisms, an under-discussed topic. Divided into two sections, researchers, professors, and students will find the wide range of topics, including the most cutting edge topics in chemistry, like the future of solar energy, catalysis, environmental issues, climate changes atmosphere, and human health, essential to understanding chemistry.

NMR in Organometallic Chemistry

Author: Paul S. Pregosin

Publisher: John Wiley & Sons

ISBN: 3527330135

Category: Science

Page: 392

View: 3307

The first and ultimate guide for anyone working in transition organometallic chemistry and related fields, providing the background and practical guidance on how to efficiently work with routine research problems in NMR. The book adopts a problem-solving approach with many examples taken from recent literature to show readers how to interpret the data. Perfect for PhD students, postdocs and other newcomers in organometallic and inorganic chemistry, as well as for organic chemists involved in transition metal catalysis.

NMR of Paramagnetic Molecules

Applications to Metallobiomolecules and Models

Author: Ivano Bertini,Claudio Luchinat,Giacomo Parigi,Enrico Ravera

Publisher: Elsevier

ISBN: 0444634487

Category: Science

Page: 508

View: 6633

NMR of Paramagnetic Molecules: Applications to Metallobiomolecules and Models, Second Edition is a self-contained, comprehensive reference for chemists, physicists, and life scientists whose research involves analyzing paramagnetic compounds. Since the previous edition of this book was published, there have been many advancements in the field of paramagnetic NMR spectroscopy. This completely updated and expanded edition contains the latest fundamental theory and methods for mastery of this analytical technique. Users will learn how to interpret the NMR spectra of paramagnetic molecules, improve experimental techniques, and strengthen their understanding of the underlying theory and applications. Reflects all advances in the field in a completely updated new edition Presents new material on self-orientation residual dipolar couplings, solid state NMR, dynamic nuclear polarization, and paramagnetic restraints for structure calculations Includes information relevant to paramagnetic molecules, metallobiomolecules, paramagnetic compounds, and paramagnetic NMR spectroscopy Presents specific examples of paramagnetic inorganic species and experimental techniques for structure characterization

Mössbauer Spectroscopy Applied to Inorganic Chemistry

Author: G.J Long

Publisher: Springer Science & Business Media

ISBN: 9780306416477

Category: Science

Page: 668

View: 9182

When presented with a new compound or material, the inorganic chemist will usually have several questions in mind about its composition and structure. Although a simple elemental analysis may answer many questions about its composition, the chemist will still have questions about its structure, and, ifthe material contains a metal atom, he will often want to know its oxidation state, coordination number and geometry. Further, at an increasingly frequent rate, the chemist may need details of the spin state, magnetic and perhaps dynamic properties of the material. If the investigator is fortunate, the material or compound may contain an ele ment such as iron, tin, antimony, iodine, gold, or one of several of the rare earth metals which are amenable to study by the Mossbauer effect. Often the Mossbauer effect can, sometimes with quite simple experiments, provide the answers to all of these questions. The goal of this book is to illustrate the effectiveness of the Mossbauer effect in providing the answers to the many questions that arise in char acterizing new materials and, indeed, in studying known materials in more detail. Several chapters introduce the effect to the novice and provide details about the various hyperfine interactions that are the "bread and butter" of the Mossbauer spectroscopist. Three chapters deal specifically with the experimental aspects of the technique and the increasing impor tance of sophisticated computer analysis of the resulting data.