Inorganic Spectroscopic Methods

Author: Alan K. Brisdon

Publisher: OUP Oxford

ISBN: 9780198559498

Category: Science

Page: 100

View: 6463

A knowledge of spectroscopic methods is required to interpret the shape and structure of compounds - this informative book concentrates on their application to inorganic compounds. The emphasis is placed on obtaining and interpreting the data rather than concentrating on the theory. To this end, examples are given in the text and worked through to show the processes involved in assigning spectra and obtaining information from them. This essential text for all undergraduate chemists will also benefit postgraduate students researching in the field of inorganic chemistry.

Spectroscopy in Inorganic Chemistry

Author: C.N.R. Rao

Publisher: Elsevier

ISBN: 032315090X

Category: Science

Page: 424

View: 5055

Spectroscopy in Inorganic Chemistry, Volume I describes the innovations in various spectroscopic methods that are particularly effective in inorganic chemistry studies. This volume contains nine chapters; each chapter discusses a specific spectroscopic method, their fundamental principles, methods, instrumentation, advantages disadvantages, and application. Chapter 1 covers some of the general principles and experiments that have been used in the recording and interpretation of crystal spectra of molecules that contain transition-metal ions. Chapter 2 illustrates the application of spectroscopic techniques to the photochemistry of small inorganic molecules, non-transition-metal compounds, and transition-metal complexes. The remaining chapters examine several spectroscopic methods, such as matrix isolation, mass, soft X-ray, and Mössbauer spectroscopies, high-resolution NMR, and nuclear quadrupole resonance, with a particular emphasis on their effective application in inorganic chemistry studies. This book will be of great benefit to inorganic chemists, spectroscopists, and inorganic chemistry teachers and students.

Spectroscopic Properties of Inorganic and Organometallic Compounds

Techniques, Materials and Applications

Author: Richard Douthwaite,Simon Duckett ,Jack Yarwood

Publisher: Royal Society of Chemistry

ISBN: 1849739196

Category: Science

Page: 299

View: 840

Divided into sections mainly according to the particular spectroscopic technique used, researchers will find this an invaluable source of information on current methods and applications.

Separation, Preconcentration and Spectrophotometry in Inorganic Analysis

Author: Z. Marczenko,Maria Balcerzak

Publisher: Elsevier

ISBN: 9780080541082

Category: Science

Page: 528

View: 5946

Spectrophotometry enables one to determine, with good precision and sensitivity, almost all the elements present in small and trace quantities of any material. The method is particularly useful in the determination of non-metals and allows the determination elements in a large range of concentrations (from single % to low ppm levels) in various materials. In Separation, Preconcentration and Spectrophotometry in Inorganic Analysis, much attention has been paid to separation and preconcentration methods, since they play an essential role in increasing the selectivity and sensitivity of spectrophotometric methods. Separation and preconcentration methods have also been utilised in other determination techniques. Spectrophotometric methods which are widely used for the determination of the elements in a large variety of inorganic materials are presented in the book whilst separation and preconcentration procedures combined with spectrophotometry are also described. This book contains recent advances in spectrophotometry, detailed discussion of the instrumentation, and the techniques and reagents used for spectrophotometric determination of elements in a wide range of materials as well as a detailed discussion of separation and preconcentration procedures that precede the spectrophotometric detection.

NMR Spectroscopy in Inorganic Chemistry

Author: Jonathan A. Iggo

Publisher: Oxford University Press, USA

ISBN: 9780198558903

Category: Science

Page: 87

View: 3802

Nuclear Magnetic Resonance (NMR) spectroscopy is the most important characterization technique in synthetic chemistry today. By giving a simple overview of the relevant theory, in non-mathematical terms, and avoiding the 'pattern recognition' approach frequently adopted, this book demystifies NMR. It contains examples from many different areas of Inorganic Chemistry which are closely related to the theory described.

Structural Methods in Molecular Inorganic Chemistry

Author: D. W. H. Rankin,Norbert Mitzel,Carole Morrison

Publisher: John Wiley & Sons

ISBN: 1118462882

Category: Science

Page: 496

View: 8468

Determining the structure of molecules is a fundamental skill that all chemists must learn. Structural Methods in Molecular Inorganic Chemistry is designed to help readers interpret experimental data, understand the material published in modern journals of inorganic chemistry, and make decisions about what techniques will be the most useful in solving particular structural problems. Following a general introduction to the tools and concepts in structural chemistry, the following topics are covered in detail: • computational chemistry • nuclear magnetic resonance spectroscopy • electron paramagnetic resonance spectroscopy • Mössbauer spectroscopy • rotational spectra and rotational structure • vibrational spectroscopy • electronic characterization techniques • diffraction methods • mass spectrometry The final chapter presents a series of case histories, illustrating how chemists have applied a broad range of structural techniques to interpret and understand chemical systems. Throughout the textbook a strong connection is made between theoretical topics and the real world of practicing chemists. Each chapter concludes with problems and discussion questions, and a supporting website contains additional advanced material. Structural Methods in Molecular Inorganic Chemistry is an extensive update and sequel to the successful textbook Structural Methods in Inorganic Chemistry by Ebsworth, Rankin and Cradock. It is essential reading for all advanced students of chemistry, and a handy reference source for the professional chemist.

Practical Approaches to Biological Inorganic Chemistry

Author: Robert R. Crichton,Ricardo O. Louro

Publisher: Newnes

ISBN: 0444563598

Category: Science

Page: 336

View: 6292

The book reviews the use of spectroscopic and related methods to investigate the complex structures and mechanisms of biological inorganic systems that contain metals. Each chapter presents an overview of the technique including relevant theory, clearly explains what it is and how it works and then presents how the technique is actually used to evaluate biological structures. Practical examples and problems are included to illustrate each technique and to aid understanding. Designed for students and researchers who want to learn both the basics, and more advanced aspects of bioinorganic chemistry. Many colour illustrations enable easier visualization of molecular mechanisms and structures Worked examples and problems are included to illustrate and test the reader’s understanding of each technique Written by a multi-author team who use and teach the most important techniques used today to analyse complex biological structures

Physical Methods in Bioinorganic Chemistry

Spectroscopy and Magnetism

Author: Lawrence Que

Publisher: Univ Science Books

ISBN: 9781891389689

Category: Science

Page: 556

View: 9319

This text provides detailed coverage of physical methods used in bioinorganic chemistry. Individual chapters are devoted to electronic absorption spectroscopy, resonance Raman spectroscopy, electron paramagnetic resonance spectroscopy, ENDOR and ESEEM, magnetic circular dichroism, Mössbauer spectroscopy, magnetism, NMR spectroscopy as applied to paramagnetic systems, and x-ray absorption spectroscopy. The book aims to provide a fundamental understanding of each method and demonstrate how data obtained from a system of bioinorganic interest can be interpreted. Case studies are presented in the last chapter in which more than one technique has been applied to gain insight into each given bioinorganic problem. By integrating theory with experimentation and providing an orientation that is more biological than that presented in previously published books, Physical Methods in Bioinorganic Chemistry: Spectroscopy and Magnetism will serve as an important new text for students of bioinorganic chemistry, biochemistry, molecular biology, and their professors.

Inorganic Chemistry

Author: Mark Weller,Tina Overton,Jonathan Rourke,Fraser Armstrong

Publisher: Oxford University Press

ISBN: 0198768125

Category:

Page: 968

View: 8864

From the fundamental principles of inorganic chemistry to cutting-edge research at the forefront of the subject, this text provides a comprehensive introduction to the field.

Inorganic Electronic Structure and Spectroscopy

Methodology

Author: Edward I. Solomon,A. B. P. Lever

Publisher: Wiley-Interscience

ISBN: 9780471971245

Category: Science

Page: 752

View: 5559

-Journal of Chemical Education This newly available paperbound edition of Inorganic Electronic Structure and Spectroscopy includes all the material from the original clothbound edition published in 1999. Consisting of articles contributed by outstanding scientists from around the world, Volume I, Methodology presents the state of the art in this field, written in a style accessible to the well-read senior undergraduate, and yet still of superior value to the senior researcher. The first of a two-volume set, Volume I provides a thorough review of methodologies in transition metal spectroscopy and theoretical modeling, including: * Electron Paramagnetic Resonance Spectroscopy * IR, Raman, and Resonance Raman Spectroscopy * Newer techniques used in inorganic chemistry, such as polarized absorption spectroscopy * Luminescence spectroscopy * Laser spectroscopy, X-ray and absorption spectroscopy, and EXAFS * Three important chapters on traditional ligand field theory This work assumes a basic understanding of quantum chemistry and group theory and reflects the current state of development for many of the techniques used by practicing inorganic chemists. Although written by multiple contributors, the editors' holistic approach to the manuscript has ensured a uniform presentation.

Infrared Spectroscopy

Fundamentals and Applications

Author: Barbara H. Stuart

Publisher: John Wiley & Sons

ISBN: 0470011130

Category: Science

Page: 242

View: 5631

Provides an introduction to those needing to use infrared spectroscopy for the first time, explaining the fundamental aspects of this technique, how to obtain a spectrum and how to analyse infrared data covering a wide range of applications. Includes instrumental and sampling techniques Covers biological and industrial applications Includes suitable questions and problems in each chapter to assist in the analysis and interpretation of representative infrared spectra Part of the ANTS (Analytical Techniques in the Sciences) Series.

Spectroscopic Properties of Inorganic and Organometallic Compounds

Techniques, Materials and Applications

Author: Jack Yarwood,Richard Douthwaite,Simon Duckett

Publisher: Royal Society of Chemistry

ISBN: 1847550479

Category: Reference

Page: 334

View: 8132

Reflecting the growing volume of published work in this field, researchers will find this book an invaluable source of information on current methods and applications.

Techniques in Inorganic Chemistry

Author: John P. Fackler, Jr.,Larry R. Falvello

Publisher: CRC Press

ISBN: 9781439815151

Category: Science

Page: 219

View: 1426

Inorganic chemistry continues to generate much current interest due to its array of applications, ranging from materials to biology and medicine. Techniques in Inorganic Chemistry assembles a collection of articles from international experts who describe modern methods used by research students and chemists for studying the properties and structures of inorganic chemicals. Crystallography and diffraction methods The book begins by examining developments in small-molecule x-ray crystallography. It identifies some of the major advances, discusses current attitudes toward crystallography and its uses, and considers challenges and future prospects. It then examines how ab initio x-ray powder diffraction (XRPD) methods are used to determine structure, with discussions on metal pyrazolates, metal imidazolates, and metal pyrimidinolates. This is followed by a description of single crystal neutron diffraction, a powerful structural technique. The text highlights what can presently be achieved in neutron diffraction and discusses future applications of neutron scattering. Quantum chemistry Reflecting the popularity of density functional calculations, the book includes a chapter that focuses on quantum chemistry. It examines the latest computational techniques and describes how these techniques can be applied to solve a wide range of real-world problems encountered in the realm of inorganic chemistry and particularly in transition metal chemistry. It also explains the intelligent use of quantum chemical methods for the determination of molecular structure, reactivity, and spectra of coordination and organometallic compounds. Spectroscopy Lastly, the text explores important spectroscopic approaches. It first describes intermolecular nuclear Overhauser effect (NOE) NMR experiments and diffusion experiments, offering examples that demonstrate theoretical aspects of the methodology. The final chapter summarizes recent experimental and theoretical work on pressure effects on the d-d and luminescence spectra of transition metal complexes. Derived from select articles in Comments on Inorganic Chemistry, this volume provides a solid background in the array of techniques available in the researcher’s toolkit.

Shriver and Atkins' Inorganic Chemistry

Author: Peter Atkins

Publisher: Oxford University Press, USA

ISBN: 0199236178

Category: Science

Page: 824

View: 4755

Inorganic Chemistry fifth edition represents an integral part of a student's chemistry education. Basic chemical principles are set out clearly in 'Foundations' and are fully developed throughout the text, culminating in the cutting-edge research topics of the 'Frontiers', which illustrate the dynamic nature of inorganic chemistry.

Spectral Methods in Transition Metal Complexes

Author: K. Sridharan

Publisher: Elsevier

ISBN: 0128096543

Category: Science

Page: 202

View: 2748

Spectral Methods in Transition Metal Complexes provides a conceptual understanding on how to interpret the optical UV-vis, vibrational EPR, and NMR spectroscopy of transition metal complexes. Metal complexes have broad applications across chemistry in the areas of drug discovery, such as anticancer drugs, sensors, special materials for specific requirements, and catalysis, so a thorough knowledge in preparation and characterization of metal complexes, while niche, is critical. Accessible to both the seasoned researcher and the graduate student alike, this book provides readers with a single source of content that addresses spectral methods in transition metal complexes. Provides readers with a single reference on metal complexes and coordination compounds Contains more than 100 figures, tables, and illustrations to aid in the retention of key concepts Authored by a scientist with nearly 40 years of experience in research and instruction

Introduction to Modern Inorganic Chemistry, 6th edition

Author: R.A. Mackay,W. Henderson

Publisher: CRC Press

ISBN: 9780748764204

Category: Science

Page: 624

View: 1843

This popular and comprehensive textbook provides all the basic information on inorganic chemistry that undergraduates need to know. For this sixth edition, the contents have undergone a complete revision to reflect progress in areas of research, new and modified techniques and their applications, and use of software packages. Introduction to Modern Inorganic Chemistry begins by explaining the electronic structure and properties of atoms, then describes the principles of bonding in diatomic and polyatomic covalent molecules, the solid state, and solution chemistry. Further on in the book, the general properties of the periodic table are studied along with specific elements and groups such as hydrogen, the 's' elements, the lanthanides, the actinides, the transition metals, and the "p" block. Simple and advanced examples are mixed throughout to increase the depth of students' understanding. This edition has a completely new layout including revised artwork, case study boxes, technical notes, and examples. All of the problems have been revised and extended and include notes to assist with approaches and solutions. It is an excellent tool to help students see how inorganic chemistry applies to medicine, the environment, and biological topics.

Organic Spectroscopic Analysis

Author: Rosaleen J. Anderson,David J. Bendell,Paul W. Groundwater

Publisher: Royal Society of Chemistry

ISBN: 9780854044764

Category: Education

Page: 176

View: 6810

A unique textbook, aimed at undergraduate students, containing large numbers of spectra, problems and marginal notes, specifically chosen to highlight the points being discussed.

Foundations of Spectroscopy

Author: Simon B. Duckett,Bruce C. Gilbert

Publisher: Oxford University Press

ISBN: 9780198503354

Category: Language Arts & Disciplines

Page: 90

View: 2371

This Primer covers the foundations of spectroscopy at a level suitable for first year chemistry undergraduates. Mass spectrometry, and X-ray diffraction, along with traditional spectroscopic techniques: i.r., n.m.r. and u.v. -visible spectroscopy are covered. The essential physical principles of each method are introduced, and many examples of spectral analysis provided. Problems, and further reading are also included. This Primer is designed to reflect the recent advances in the use of spectroscopic and diffraction methods, not only for obtaining an analysis of elements and groups present in a molecule but also for establishing the arrangement of the constituent atoms. These developments have had a profound effect by increasing scientific knowledge in the fields of chemistry and molecular biology, reflected in the elucidation of the structure and function of a wide range of compounds including drugs, proteins and enzymes, and nucleic acids.

Modern Spectroscopy

Author: J. Michael Hollas

Publisher: John Wiley & Sons

ISBN: 0470094710

Category: Science

Page: 480

View: 8380

The latest edition of this highly acclaimed title introduces the reader to a wide range of spectroscopies, and includes both the background theory and applications to structure determination and chemical analysis. It covers rotational, vibrational, electronic, photoelectron and Auger spectroscopy, as well as EXAFs and the theory of lasers and laser spectroscopy. A revised and updated edition of a successful, clearly written book Includes the latest developments in modern laser techniques, such as cavity ring-down spectroscopy and femtosecond lasers Provides numerous worked examples, calculations and questions at the end of chapters

Frontiers of Molecular Spectroscopy

Author: Jaan Laane

Publisher: Elsevier

ISBN: 9780080932378

Category: Science

Page: 740

View: 7386

Much of what we know about atoms, molecules, and the nature of matter has been obtained using spectroscopy over the last one hundred years or so. In this book we have collected together twenty chapters by eminent scientists from around the world to describe their work at the cutting edge of molecular spectroscopy. These chapters describe new methodology and applications, instrumental developments, and theory which is taking spectroscopy into new frontiers. The range of topics is broad. Lasers are utilized in much of the research, but their applications range from sub-femtosecond spectroscopy to the study of viruses and also to the investigation of art and archeological artifacts. Three chapters discuss work on biological systems and three others represent laser physics. The recent advances in cavity ringdown spectroscopy (CRDS), surface enhanced Raman spectroscopy (SERS), two-dimensional correlation spectroscopy (2D-COS), and microwave techniques are all covered. Chapters on electronic excited states, molecular dynamics, symmetry applications, and neutron scattering are also included and demonstrate the wide utility of spectroscopic techniques. * provides comprehensive coverage of present spectroscopic investigations * features 20 chapters written by leading researchers in the field * covers the important role of molecular spectroscopy in research concerned with chemistry, physics, and biology