Chemical Bonding

Author: M.S. Sethi & M. Satake

Publisher: Discovery Publishing House

ISBN: 9788171411634


Page: 156

View: 3172

Contents: Chemical Bonding-I : Basic Concepts, Chemical Bonding-II : Additional Aspects, Intermolecular Force and Crystal Structures.

Molecules and the Chemical Bond

Author: Henry A. Bent

Publisher: Trafford Publishing

ISBN: 1426962991

Category: Education

Page: 404

View: 2242

MOLECULES AND THE CHEMICAL BOND & Other Leading Chemical Concepts Simplified This highly original book by a noted chemist and chemical educator may change the way newcomers to chemical thought learn and the way its connoisseurs think about - * Atomic Theory * The Mole Concept and Avogadro's Constant * The Gas Laws * Solving Problems in Chemical Stoichiometry * The Saturation and Directional Character of Chemical Affinity * The Pauli Exclusion Principle * Linnett's Double Spin Set Theory * Pauling's Rules of Crystal Chemistry * The Octet Rule * Lewis Structures for O2, NO, CO, SO2 and SO3 * Construction of Bond Diagrams * VSEPR Theory * Dative Bonding * Multicenter Bonding * Bonding in Metals * pH Calculations * The Periodic Table * The Energy Function and the First Law of Thermodynamics * The Entropy Function and the Second Law of Thermodynamics * How an Inductive Science Advances Dedicated to students, teachers, and professionals in the pure and applied sciences who might welcome an account of molecular structure that, in Einstein's words is as simple as possible but [it's believed] no simpler and that provides, thereby, in Gibbs' words, a point of view from which the subject appears in its greatest simplicity, MCB is several books interlaced. It is a novel account of evidence for atoms; an historical account of the development classical structural theory of molecules; a simple, step-by-step guide on how to draw scientifically sound bond diagrams; an exclusive orbital model of bonding that embraces from one point of view covalent, ionic, and metallic bonding; philosophical justifications for uses of molecular models; explanations for a number of previously unexplained molecular features; domestication for easy use in valence theory of fundamental principles of quantum physics; and, withal, a short textbook of general chemistry in a new key. Principally MCB is a highly visual account of a chemical mechanics of the Pauli Exclusion Principle, in the form of the story of a stroke, a stick, and a sphere and what happens if one takes chemists' seemingly unsophisticated cartoons of molecules and their corresponding tinker-toy-like ball-and-stick models seriously. One theme runs through the book: the nature of the inductive sciences, illustrated by the union of facts and ideas with creation of concepts and models, principles and rules that, jointly, comprise what is called in MCB "Conceptual Valence Bond Theory". The book has been described "as a pedagogical hierarchy of progressively more sophisticated treatments of an easily visualizable model of the chemical bond." In the words of the author's daughter (a chemist) - "This book is the culmination of my Father's insights into the molecules he has literally breathed, consumed, and digested, for the past 84 years. It is his intimate knowledge about the elements, learned from a lifetime of reading, experimenting, and teaching that makes this book different. Dad truly loves (and believes in!) molecules, and that single tenet comes across on every page. Flat valence stroke diagrams are inflated to three dimensional valence sphere models whose geometries correlate with calculations and provide, with ease, explanations for reaction mechanisms, multicenter bonds, and molecular geometries considered exceptions or unexpected . Describing molecules as hypervalent or electron deficient suggests something abnormal or unnatural, and is misleading since nature is always natural . Concepts such as the gas laws and the energy function are presented from an historical perspective, and with algebraic rigor, eliminating inconsistencies that bug you as a chemistry student, but you can't really put your finger on why. From the correct placement of helium above beryllium in the periodic table, to pointing out the problems with omitting nucleus-electron attractions in the popular Valence Shell Electron Pair Repulsion theory (where correct conclusions regarding molecular shapes support an incorrect conce

Electronic Structure and Chemical Bonding

Author: J. R. Lalanne,R. Boisgard

Publisher: World Scientific

ISBN: 9789810226657

Category: Science

Page: 292

View: 1571

This book addresses the problem of teaching the Electronic Structure and Chemical Bonding of atoms and molecules to high school and university students. It presents the outcomes of thorough investigations of some teaching methods as well as an unconventional didactical approach which were developed during a seminar for further training organized by the University of Bordeaux I for teachers of the physical sciences.The text is the result of a collective effort by eleven scientists and teachers: physicists and chemists doing research at the university or at the CRNS, university professors, and science teachers at high-school or university level.While remaining wide open to the latest discoveries of science, the text also offers a large number of problems along with their solutions and is illustrated by several pedagogic suggestions. It is intended for the use of teachers and students of physics, chemistry, and of the physical sciences in general.

Chemical Bonds

Author: Phillip Manning

Publisher: Infobase Publishing

ISBN: 0791097404

Category: Juvenile Nonfiction

Page: 134

View: 9309

Reaching beyond the typical high school chemistry textbook, each title in this series offers real-life, concrete examples that illustrate the practical importance of the topic at hand, and includes a full-color periodic table, color photographs, sidebars, and a glossary.

The Chemical Bond

Fundamental Aspects of Chemical Bonding

Author: Gernot Frenking,Sason Shaik

Publisher: John Wiley & Sons

ISBN: 3527664718

Category: Science

Page: 438

View: 9366

This is the perfect complement to "Chemical Bonding - Across the Periodic Table" by the same editors, who are two of the top scientists working on this topic, each with extensive experience and important connections within the community. The resulting book is a unique overview of the different approaches used for describing a chemical bond, including molecular-orbital based, valence-bond based, ELF, AIM and density-functional based methods. It takes into account the many developments that have taken place in the field over the past few decades due to the rapid advances in quantum chemical models and faster computers.

Chemical Bonding at Surfaces and Interfaces

Author: Anders Nilsson,Lars G.M. Pettersson,Jens Norskov

Publisher: Elsevier

ISBN: 9780080551913

Category: Science

Page: 532

View: 1016

Molecular surface science has made enormous progress in the past 30 years. The development can be characterized by a revolution in fundamental knowledge obtained from simple model systems and by an explosion in the number of experimental techniques. The last 10 years has seen an equally rapid development of quantum mechanical modeling of surface processes using Density Functional Theory (DFT). Chemical Bonding at Surfaces and Interfaces focuses on phenomena and concepts rather than on experimental or theoretical techniques. The aim is to provide the common basis for describing the interaction of atoms and molecules with surfaces and this to be used very broadly in science and technology. The book begins with an overview of structural information on surface adsorbates and discusses the structure of a number of important chemisorption systems. Chapter 2 describes in detail the chemical bond between atoms or molecules and a metal surface in the observed surface structures. A detailed description of experimental information on the dynamics of bond-formation and bond-breaking at surfaces make up Chapter 3. Followed by an in-depth analysis of aspects of heterogeneous catalysis based on the d-band model. In Chapter 5 adsorption and chemistry on the enormously important Si and Ge semiconductor surfaces are covered. In the remaining two Chapters the book moves on from solid-gas interfaces and looks at solid-liquid interface processes. In the final chapter an overview is given of the environmentally important chemical processes occurring on mineral and oxide surfaces in contact with water and electrolytes. Gives examples of how modern theoretical DFT techniques can be used to design heterogeneous catalysts This book suits the rapid introduction of methods and concepts from surface science into a broad range of scientific disciplines where the interaction between a solid and the surrounding gas or liquid phase is an essential component Shows how insight into chemical bonding at surfaces can be applied to a range of scientific problems in heterogeneous catalysis, electrochemistry, environmental science and semiconductor processing Provides both the fundamental perspective and an overview of chemical bonding in terms of structure, electronic structure and dynamics of bond rearrangements at surfaces

Elektronen und Chemische Bindung

Author: Harry B. Gray

Publisher: Walter de Gruyter

ISBN: 3110830620

Category: Reference

Page: 205

View: 1836

“Electrons and chemical bonding: This standard textbook on quantum chemistry is easy to understand even for chemists; its basic concepts never become obsolete. Well done didactically, concise and to-the-point.” Prof. Dr. Ralf Steudel, TU Berlin

Chemical bonds

a dialog

Author: Jeremy K. Burdett

Publisher: John Wiley & Son Ltd

ISBN: 9780471971290

Category: Science

Page: 166

View: 6133

* an orbital approach to quantum chemistry

Chemical Bonding for JEE Main & Advanced, NEET 2nd Edition

Author: Vaibhav Trivedi

Publisher: Disha Publications

ISBN: 9387421740


Page: 200

View: 5595

The thoroughly revised & updated 2nd edition of the book on Chemical Bonding is designed especially in accordance with latest competitive trends. The book has been updated with the past questions of NEET, JEE Main & JEE Advanced. A new chapter entitled 'Hydrolysis of Covalent Compounds' has been added based on student's high demand. The salient features of the book are as follows: * A moderately concise and compact book covering all topics from A –Z. * Bent Rule with latest amendments and Drago’s Rule * Physical properties of ionic & covalent compounds with detailed explanation. * Increasing and decreasing order of lattice energy, hydration energy, polarization and effect of these on physical properties has been done comparatively. * Simple language to make it useful even to average and weak students. * Logical and evolutionary approach in descriptions for better imagination and visualization. * Large no. of solved examples, illustrations and Objective type questions. * Miscellaneous Practice Problems as final challenge.

X-Ray Charge Densities and Chemical Bonding

Author: Philip Coppens

Publisher: International Union of Crystallography

ISBN: 9780195356946

Category: Science

Page: 384

View: 6014

This book deals with the electron density distribution in molecules and solids as obtained experimentally by X-ray diffraction. It is a comprehensive treatment of the methods involved, and the interpretation of the experimental results in terms of chemical bonding and intermolecular interactions. Inorganic and organic solids, as well as metals, are covered in the chapters dealing with specific systems. As a whole, this monograph is especially appealing because of its broad interface with numerous disciplines. Accurate X-ray diffraction intensities contain fundamental information on the charge distribution in crystals, which can be compared directly with theoretical results, and used to derive other physical properties, such as electrostatic moments, the electrostatic potential and lattice energies, which are accessible by spectroscopic and thermodynamic measurements. Consequently, the work will be of great interest to a broad range of crystallographers and physical scientists.

Chemical Bonds

An Introduction to Atomic and Molecular Structure

Author: Harry B. Gray

Publisher: University Science Books

ISBN: 9780935702354

Category: Chemical bonds

Page: 232

View: 9188

Absorption Spectra and Chemical Bonding in Complexes

Author: C. K. Jørgensen

Publisher: Elsevier

ISBN: 148318465X

Category: Science

Page: 368

View: 7316

Absorption Spectra and Chemical Bonding in Complexes focuses on chemical bonding in transition group complexes and molecules, including molecular orbitals, absorption bands, and energy levels. The book first outlines the history of chemical bonding, giving emphasis to different theories that paved the way for further studies in this field. The text then examines the energy levels of a configuration and molecular orbitals and microsymmetry. The publication takes a look at the interelectronic repulsion in M.O. configurations, the characteristics of absorption bands, and spectrochemical series. Electron transfer spectra, energy levels in complexes with almost spherical symmetry, molecular orbitals lacking spherical symmetry, and chemical bonding are also discussed. The book examines the determination of complex species in solution and their formation constants; survey of the chemistry of heavy, metallic elements; and tables of absorption spectra. The manuscript is a dependable source of data for physicists and group theorists interested in absorption spectra and chemical bonding.

Chemical Bonding

Covalent Bond, Hydrogen Bond, Chemical Bond, Intermolecular Force, Electronegativity, Ionic Bond, Pauli Exclusion Principle, Molecul

Author: Source Wikipedia


ISBN: 9781230562858


Page: 158

View: 2780

Please note that the content of this book primarily consists of articles available from Wikipedia or other free sources online. Pages: 157. Chapters: Covalent bond, Hydrogen bond, Chemical bond, Intermolecular force, Electronegativity, Ionic bond, Pauli exclusion principle, Molecular orbital, Metallic bond, Disulfide bond, Atomic orbital, Dipolar bond, Ligand, Peptide bond, Van der Waals force, Mesomeric effect, Electron counting, Cooperative binding, Covalent radius, Aromaticity, Hypervalent molecule, Halogen bond, Quantum mechanical explanation of intermolecular interactions, Molecular orbital diagram, Radical, Hyperconjugation, Resonance, Polyhedral skeletal electron pair theory, Orbital hybridisation, Electron affinity, Crystal field theory, Anodic bonding, Ruggero Santilli, Salt bridge, Non-innocent ligand, Chemical polarity, Lewis structure, Valence, Valence electron, Quintuple bond, Coordination geometry, Bonding in solids, Walsh diagram, Hapticity, 18-Electron rule, Electrovalency, Ligand field theory, Conjugated system, Lennard-Jones potential, Bent's rule, Inert pair effect, Atoms in molecules, Cation-pi interaction, Jahn-Teller effect, Dihydrogen complex, Valence bond theory, Bent bond, Morse potential, Hydrophobic effect, Stacking, Lanthanide contraction, Formal charge, Octet rule, Entropic force, London dispersion force, Slater's rules, Coordination number, Metal ligand multiple bond, Aurophilicity, Linear combination of atomic orbitals molecular orbital method, Agostic interaction, Inductive effect, Electron localization function, Intercalation, Double bond rule, Bond valence method, Wafer bonding, Pyramidal alkene, Bound state, Catch bond, Cooperativity, Metal aromaticity, Three-center four-electron bond, Sextuple bond, Chemical bonding model, Antibonding, Sigma bond, Denticity, Pi bond, Noncovalent bonding, Cubical atom, Dihydrogen bond, Hydrophile, D-block contraction, Chemical change, Delocalized electron, Linkage isomerism, Keating Model, ..

Metal-Polymer Systems

Interface Design and Chemical Bonding

Author: Jörg Friedrich

Publisher: John Wiley & Sons

ISBN: 3527679928

Category: Technology & Engineering

Page: 400

View: 4189

The result of decades of research by a pioneer in the field, this is the first book to deal exclusively with achieving high-performance metal-polymer composites by chemical bonding. Covering both the academic and practical aspects, the author focuses on the chemistry of interfaces between metals and polymers with a particular emphasis on the chemical bonding between the different materials. He elucidates the various approaches to obtaining a stable interface, including, but not limited to, thermodynamically driven redox reactions, bond protection to prevent hydrolysis, the introduction of barrier layers, and stabilization by spacer molecules. Throughout, chemical bonding is promoted as a simple and economically viable alternative to adhesion based on reversible weak physical interaction. Consequently, the text equips readers with the practical tools necessary for designing high-strength metal-polymer composites with such desired properties as resilience, flexibility, rigidity or degradation resistance.